Saturday, June 22, 2013

From combinatorics to entropy

From combinatorics to entropy:
Let N=n1+...+nk and pi=niN.
log(N!n1!...nk!)Nipilogpi
by Stirling's formula.

I wonder if this was the first time ever in human history that such an expression ipilogpi appeared! Entropy is often too abstract to me. The approximation above is a link between counting combinations and entropy, and it seems to provide the most concrete grasp~
This is the genius of Boltzmann, Maxwell and Gibbs which leads to the development of statistical mechanics.

Energy, entropy, free energy, enthalpy, Legendre transform, etc. are still difficult to understand to me.



Renyi/generalized entropy:
Dq=1q1logipiq
It is related to the generalized dimension dimq(μ) and Lq-spectrum τ(q):=lim infr01logrlogsupiμ(Bi)q:
dimq(μ)=limr0Dqlogr=τ(q)q1.

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